Here's a list of Honorifics used amongst the Adventure characters. I figured it would be helpful to people looking into this topic.
Taichi:
Mimi-chan
Miyako-chan
Taichi never speaks with Ken directly, so we don't know if he would use any honorific with him.
He refers to everyone else with no honorifics.
Yamato:
Hikari-chan
Miyako-chan
Yamato never speaks with Mimi or Ken directly, so we don't know if he would use any honorific with them.
He refers to everyone else with no honorifics.
Sora:
Yamato-kun
Koushiro-kun
Jyou-sempai
Mimi-chan
Takeru-kun
Hikari-chan
Daisuke-kun
Miyako-chan
Iori-kun
Sora never speaks with Ken directly, so we don't know if she would use any honorific with him.
She does not use an honorific when speaking with Taichi.
Koushirou:
Taichi-san
Yamato-san
Sora-san
Jyou-san
Mimi-san
Takeru-kun
Hikari-san
Daisuke-kun
Miyako-kun (my assumption for -kun being used here is due to them both being part of the computer club. -kun can at times to used for females in the office / when part of a group project)
Iori-kun
Ichijouji-kun
Jyou:
Sora-kun
Mimi-kun
Hikari-kun
Jyou never speaks with Miyako directly, so we don't know if he would use any honorific with her.
Jyou refers to everyone else with no honorific.
Jyou referring to all females with -kun boggles the mind. One would think he'd only ever spoken to other boys before Adventure began.
Mimi:
Taichi-san
Sora-san
Koushirou-kun
Jyou-sempai
Takeru-kun
Hikari-chan
Daisuke-kun
Miyako-chan
Mimi never speaks with Yamato, Iori and Ken directly, so we don't know if she would use any honorific with them.
Takeru:
Taichi-san
Sora-san
Koushirou-san
Jyou-san
Mimi-san
Hikari-chan
Daisuke-kun
Miyako-san
Iori-kun
He refers to Ken with Ichijouji-kun.
He refers to Yamato with Oniichan (older brother).
Hikari:
Yamato-san
Sora-san
Koushirou-san
Jyou-san
Mimi-san
Takeru-kun
Daisuke-kun
Miyako-san
Iori-kun
Ichijouji-kun
She refers to Taichi with Oniichan (older brother).
Daisuke:
Yamato-san
Jyou-san
Mimi-san
Hikari-chan
Daisuke variates between Taichi-sempai and Taichi-san. He uses Taichi-sempai when Taichi is actually in earshot, and Taichi-san when he isn't.
He never speaks with Sora directly, so we don't know if he would use any honorific with her.
He refers to everyone else with no honorifics.
Miyako:
Taichi-san
Sora-san
Izumi-sempai
Mimi-san
Hikari-chan
Ken-kun
Miyako never speaks with Yamato, Jyou, and Takeru directly, so we don't know if she would use any honorific with them.
She does not use an honorific when speaking with Daisuke and Iori.
Iori:
Taichi-san
Yamato-san
Koushirou-san
Jyou-san
Takeru-san
Hikari-san
Daisuke-san
Miyako-san
Ichijouji-san
Iori never speaks with Sora and Mimi directly, so we don't know if he would use any honorific with them.
Ken:
Yamato-san
Izumi-san
Hikari-san
Miyako-san
Iori-kun
Ken never speaks with Taichi, Sora, Jyou, Mimi, or Takeru directly, so we don't know if he would use any honorific with them.
Source:
Honorifics used in Digimon